Solubility, stability, and electrochemical studies of sulfur-sulfide solutions in organic solvents

A preliminary study of the sulfur electrode in organic solvents suggests that the system warrants further investigation for use in a low temperature (100 deg to 120 C) Na-S secondary battery. A qualitative screening was undertaken at 120 C to determine the solubilities and stabilities of Na2S and Na2S2 in representatives of many classes of organic solvents. From the screening and quantitative studies, two classes of solvents were selected for work; amides and cyclic polyalcohols. Voltammetric and Na-S cell charge discharge studies of sulfide solutions in organic solvents (e.g., N, N-dimethylformamide) at 120 C suggested that the reversibilities of the reactions on Pt or high density graphite were moderately poor. However, the sulfur electrode was indeed reducible (and oxidizable) through the range of elemental sulfur to Na2S. Reactions and mechanisms are proposed for the oxidation reduction processes occurring at the sulfur electrode

Magnetic susceptibility variations in Loess sequences and their relationship to astronomical forcing

The long, well-exposed and often continuous sequences of loess found throughout the world are generally thought to provide an excellent opportunity for studying long-term, large-scale environmental change during the last few million years. In recent years, the most fruitful loess studies have been those involving the deposits of the loess in China. One of the most intriguing results of that work has been the discovery of an apparent correlation between variations in the magnetic susceptibility of the loess sequence and the oxygen isotope record of the deep sea. This correlation implies that magnetic susceptibility variations are being driven by astronomical parameters. However, the basic data have been interpreted in various ways by different authors, most of whom assumed that the magnetic minerals in the loess have not been affected by post-depositional processes. Using a chemical extraction procedure that allows us to separate the contribution of secondary pedogenic magnetic minerals from primary inherited magnetic minerals, we have found that the magnetic susceptibility of the Chinese paleosols is largely due to a pedogenic component which is present to a lesser degree in the loess. We have also found that the smaller inherited component of the magnetic susceptibility is about the same in the paleosols and the loess. These results demonstrate the need for additional study of the processes that create magnetic susceptibility variations in order to interpret properly the role of astronomical forcing in producing these variations

ULF waves in the solar wind as direct drivers of magnetospheric pulsations

[1] Global magnetospheric ULF pulsations with frequencies in the Pc 5 range (f = 1.7–6.7 mHz) and below have been observed for decades in space and on the Earth. Recent work has shown that in some cases these pulsations appear at discrete frequencies. Global cavity and waveguide modes have been offered as possible sources of such waves. In these models the magnetosphere is presumed to resonate globally at frequencies determined solely by its internal properties such as size, shape, field topology, mass density distribution, etc. We show in this work that upstream solar wind number density and dynamic pressure variations precede and drive compressional magnetic field variations at geosynchronous orbit. Furthermore, spectral analysis shows that wave power spectra in both the solar wind and magnetosphere contain peaks at the same discrete frequencies. Therefore, in contrast to the cavity mode hypothesis, we suggest that discrete ULF pulsations observed within the magnetosphere are at least sometimes directly driven by density oscillations present in the ambient solar wind. Finally, we comment on possible sources for such pulsations observed in the solar wind

Search for solid conductors of Na(+) and K(+) ions: Five new conductors

Five conductors of three structure types were discovered which, as solids, can transport Na(+) or K(+) ions with conductivities of approximately .00001/(omega cm) at 300 K. These compounds are: (1) the pyrochlores NaTaWO6 and NaTa2O5F, both with an activation energy for conduction delta E of 21 kJ/mole; (2) the bodycentered cubic form of NaSbO3, with delta E = 42 kJ/mole; and (3) the niobates 2Na2O with 3Nb2O5 and 2K2O with 3Nb2O5, with the alkali ions probably in open layers of the incompletely determined structure; delta E = 17 kJ/mole. On the basis of approximately 40 structure types, some generalizations were made regarding the relation between structure and ionic transport

Pushy or a Princess? Women Experts and British Broadcast News

Four times as many males as females appeared as experts on flagship television and radio news programmes in the United Kingdom as of the early 2010s. This study draws on four complementary sets of data to explore the reasons behind this disparity. The findings point to a combination of journalists’ news production processes and women’s perceptions of appropriate social norms and roles. A high proportion of woman experts surveyed lack confidence, saying they fear they will be perceived as self-promoting and “pushy” for wanting to appear on air. Broadcast journalists report women need to be persuaded and wooed, acting like “princesses” and therefore making male experts less trouble to recruit

Conductivity of boules of single crystal sodium beta-alumina

The ionic and electrochemical polarization characteristics of two boules of single crystal sodium beta-alumina (Na2O.8Al2O3), 2 cm in diameter, were investigated over the range of 25 to 300 C using 2- and 4-probe ac and dc techniques with reversible and ion-blocking electrodes. Textural (or internal) polarization at 27 C was present only in boule 1 which cleaved easily. Interfacial polarization, using solid sodium electrodes, was present at 27 C in the 2-probe conductivities for both boules. Cleaning with liquid sodium at 300 C reduced its magnitude, but some interfacial polarization was still present in the 2-probe conductivities for boule 2 below about 140 C. Above 140 C, with liquid sodium electrodes, the 2-probe conductivities, essentially polarization-free, were given by KT = 3300 exp(-3650/RT). The conductivity of boule 2 at 180 C remained essentially constant with increasing current density up to about 140 milliamps per square centimeter

A quantitative assessment of empirical magnetic field models at geosynchronous orbit during magnetic storms

[1] We evaluate the performance of recent empirical magnetic field models (Tsyganenko, 1996, 2002a, 2002b; Tsyganenko and Sitnov, 2005, hereafter referred to as T96, T02 and TS05, respectively) during magnetic storm times including both pre- and post-storm intervals. The model outputs are compared with GOES observations of the magnetic field at geosynchronous orbit. In the case of a major magnetic storm, the T96 and T02 models predict anomalously strong negative Bz at geostationary orbit on the nightside due to input values exceeding the model limits, whereas a comprehensive magnetic field data survey using GOES does not support that prediction. On the basis of additional comparisons using 52 storm events, we discuss the strengths and limitations of each model. Furthermore, we quantify the performance of individual models at predicting geostationary magnetic fields as a function of local time, Dst, and storm phase. Compared to the earlier models (T96 and T02), the most recent storm-time model (TS05) has the best overall performance across the entire range of local times, storm levels, and storm phases at geostationary orbit. The field residuals between TS05 and GOES are small (≤3 nT) compared to the intrinsic short time-scale magnetic variability of the geostationary environment even during non-storm conditions (∼24 nT). Finally, we demonstrate how field model errors may affect radiation belt studies when estimating electron phase space density

Modeling radiation belt radial diffusion in ULF wave fields: 1. Quantifying ULF wave power at geosynchronous orbit in observations and in global MHD model

[1] To provide critical ULF wave field information for radial diffusion studies in the radiation belts, we quantify ULF wave power (f = 0.5–8.3 mHz) in GOES observations and magnetic field predictions from a global magnetospheric model. A statistical study of 9 years of GOES data reveals the wave local time distribution and power at geosynchronous orbit in field-aligned coordinates as functions of wave frequency, solar wind conditions (Vx, ΔPd and IMF Bz) and geomagnetic activity levels (Kp, Dst and AE). ULF wave power grows monotonically with increasing solar wind Vx, dynamic pressure variations ΔPd and geomagnetic indices in a highly correlated way. During intervals of northward and southward IMF Bz, wave activity concentrates on the dayside and nightside sectors, respectively, due to different wave generation mechanisms in primarily open and closed magnetospheric configurations. Since global magnetospheric models have recently been used to trace particles in radiation belt studies, it is important to quantify the wave predictions of these models at frequencies relevant to electron dynamics (mHz range). Using 27 days of real interplanetary conditions as model inputs, we examine the ULF wave predictions modeled by the Lyon-Fedder-Mobarry magnetohydrodynamic code. The LFM code does well at reproducing, in a statistical sense, the ULF waves observed by GOES. This suggests that the LFM code is capable of modeling variability in the magnetosphere on ULF time scales during typical conditions. The code provides a long-missing wave field model needed to quantify the interaction of radiation belt electrons with realistic, global ULF waves throughout the inner magnetosphere

Solar pond power plant feasibility study for Davis, California

The feasibility of constructing a solar pond power plant at Davis, California was studied. Site visits, weather data compilation, soil and water analyses, conceptual system design and analyses, a material and equipment market survey, conceptual site layout, and a preliminary cost estimate were studied. It was concluded that a solar pond power plant is technically feasible, but economically unattractive. The relatively small scale of the proposed plant and the high cost of importing salt resulted in a disproportionately high capital investment with respect to the annual energy production capacity of the plant. Cycle optimization and increased plant size would increase the economical attractiveness of the proposed concept